Diaqua-bis-[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl-κN)nicotinato-κN]manganese(II)

Peng Gao; Ji-Zhong Liu; Zhong Zhang; Zhong-Jing Huang

doi:10.1107/S1600536810048506

Diaqua-bis-[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl-κN)nicotinato-κN]manganese(II)

Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 27;66(Pt 12):m1668. doi: 10.1107/S1600536810048506.

Authors

Peng Gao¹, Ji-Zhong Liu, Zhong Zhang, Zhong-Jing Huang

Affiliation

¹ Department of Chemistry, Guangxi University for Nationalities, Nanning 530006, People's Republic of China.

Abstract

In the title compound, [Mn(C(13)H(14)N(3)O(3))(2)(H(2)O)(2)], the Mn(II) ion is coordinated by four N atoms from two (±)-2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinate ligands and two water mol-ecules in a distorted octa-hedral environment. Inter-molecular O-H⋯O hydrogen bonds lead to a chain along [010]. Intra-molecular N-H⋯O and O-H⋯O hydrogen bonds are observed.