Surface characterization of Ti and Y-TZP following non-thermal plasma exposure

J Biomed Mater Res B Appl Biomater. 2011 Oct;99(1):199-206. doi: 10.1002/jbm.b.31887. Epub 2011 Jun 28.

Abstract

Novel non-thermal plasma (NTP) technology has the potential to address the bonding issues of Y-TZP and Ti surfaces. This study aims to chemically characterize and evaluate the surface energy (SE) of Y-TZP and Ti surfaces after NTP application. Y-TZP and Ti discs were treated with a hand-held NTP device followed by SE evaluation. Spectra of Y-TZP 3d and Ti 2p regions, survey scans, and quantification of the elements were performed via X-ray photoelectron Spectroscopy (XPS) prior and after NTP. Separate Y-TZP and Ti discs were NTP treated for contact angle readings using (10-methacryloyloxydecyl dihydrogenphosphate) MDP primer. Significant augmentation of SE values was observed in all NTP treated groups. XPS detected a large increase in the O element fraction on both Y-TZP and Ti surfaces. Reduction of contact angle reading was obtained when the MDP primer was placed on NTP treated Y-TZP. Ti surface showed high SE before and after NTP application on Ti surfaces. NTP decreased C and increased O on both surfaces independently of application protocol. Wettability of MDP primer on Y-TZP was significantly increased after NTP. The high polarity obtained on Y-TZP and Ti surfaces after NTP applications appear promising to enhance bonds.

Publication types

  • Evaluation Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Materials Testing
  • Photoelectron Spectroscopy
  • Plasma Gases / chemistry
  • Surface Properties
  • Titanium / chemistry*
  • Wettability
  • Yttrium / chemistry*
  • Zirconium / chemistry*

Substances

  • Plasma Gases
  • yttria stabilized tetragonal zirconia
  • Yttrium
  • Zirconium
  • Titanium