Total synthesis of (-)-anamarine
- PMID: 21739986
- DOI: 10.1021/jo2010389
Total synthesis of (-)-anamarine
Abstract
Total synthesis of polyhydroxy δ-pyranone natural product (-)-anamarine is accomplished from D-(-)-tartaric acid. The main feature of the synthesis is the utility of hitherto unexplored β-keto phosphonate derived from tartaric acid amide and further elaboration involving stereoselective reduction.
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