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. 2011 Aug 19;76(16):6889-93.
doi: 10.1021/jo2010389. Epub 2011 Jul 22.

Total synthesis of (-)-anamarine

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Total synthesis of (-)-anamarine

Kavirayani R Prasad et al. J Org Chem. .

Abstract

Total synthesis of polyhydroxy δ-pyranone natural product (-)-anamarine is accomplished from D-(-)-tartaric acid. The main feature of the synthesis is the utility of hitherto unexplored β-keto phosphonate derived from tartaric acid amide and further elaboration involving stereoselective reduction.

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