The purification of Q-containing tRNAs by periodate modification. Purification and nucleoside composition of two related Drosophila tyrosine tRNAs

Biochim Biophys Acta. 1979 Jan 26;561(1):194-205. doi: 10.1016/0005-2787(79)90502-1.

Abstract

A simple procedure for the purification of Drosophila tRNAs which contain the hypermodified nucleoside Q was developed. The cis-diol group of Q renders it susceptible to attack by sodium periodate, with the resultant formation of a hydrophobic pyrrol ring structure. The increase in hydrophobicity after periodate modification, of those tRNA species which contain the Q nucleoside, causes them to be selectively retarded on benzoylated DEAE-cellulose or RPC-5 columns, and allows their isolation in essentially pure form. Utilizing this property, the Q-containing tyrosine tRNA from Drosophila, tRNATyr1delta, was purified. The non-Q-containing tyrosine tRNA, tRNA, tRNATyr1gamma, was also purified, and the nucleoside compositions of the two were determined and compared. In addition to the Q nucleoside, these tRNAs appear to differ by the presence (tRNATyr1delta) or absence (tRNATyr1gamma) of 5-methylcytidine. In all other respects, these tRNAs appear to be identical, and are probably products of the same gene which differ in their levels of post-transcriptional modification.

MeSH terms

  • Animals
  • Base Sequence
  • Chromatography / methods
  • Drosophila / genetics
  • Guanosine / analogs & derivatives
  • Guanosine / analysis
  • Periodic Acid
  • RNA, Transfer / analysis
  • RNA, Transfer / isolation & purification*
  • Tyrosine

Substances

  • Periodic Acid
  • Guanosine
  • Tyrosine
  • RNA, Transfer