Pore partition effect on gas sorption properties of an anionic metal-organic framework with exposed Cu2+ coordination sites

Chem Commun (Camb). 2011 Oct 14;47(38):10647-9. doi: 10.1039/c1cc14118j. Epub 2011 Aug 30.

Abstract

Presented here is an anionic nanoporous framework material with mobile guest cations which can perform ion exchanges with different tetraalkylammonium cations, and the resulting tunable pore structures exhibit interesting pore partition effects on gas storage and separation.