Unique Pt5 metallacycle: [Pt(II)Cl(pyrrolidinedithiocarbamate)]5

Dalton Trans. 2011 Nov 7;40(41):10809-11. doi: 10.1039/c1dt11475a. Epub 2011 Sep 8.

Abstract

The neutral complex [PtCl(PyDT)](5) (PyDT = (CH(2))(4)NCS(2)(-)) represents the first example of a Pt(5) metallacycle. This unique architecture based on chiral S-bridged Pt(II) monomers was prepared by thermal degradation of the reaction product of PtCl(2) and a pyrrolidinedithioester.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Coordination Complexes / chemistry*
  • Crystallography, X-Ray
  • Molecular Conformation
  • Platinum / chemistry*
  • Pyrrolidines / chemistry*
  • Stereoisomerism
  • Thiocarbamates / chemistry*

Substances

  • Coordination Complexes
  • Pyrrolidines
  • Thiocarbamates
  • pyrrolidine dithiocarbamic acid
  • Platinum