Optical and electrical properties of colloidal (spherical Au)-(spinel ferrite nanorod) heterostructures

Nanoscale. 2011 Nov;3(11):4647-54. doi: 10.1039/c1nr10768b. Epub 2011 Sep 27.

Abstract

We report here a simple synthetic route to Au-Fe(x)O(y) heterostructures in which spinel ferrite (Fe(x)O(y)) grows as a nanorod on a spherical gold (Au) seed. The large red shift in the plasmon resonance in the heterostructures could be explained by a dielectric effect (although we could not entirely exclude a contribution due to electron transfer from Au to defect states at the Au-Fe(x)O(y) interface), while the magnetic properties of the Au-Fe(x)O(y) heterostructures were basically the same as those of the corresponding nanocrystals after Au leaching. In films of Au-Fe(x)O(y) heterostructures the electrical conductivity appeared to be mediated by the Au domains.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Colloids / chemistry
  • Electric Conductivity
  • Ferric Compounds / chemistry*
  • Gold / chemistry*
  • Materials Testing
  • Nanostructures / chemistry*
  • Nanostructures / ultrastructure*
  • Particle Size
  • Refractometry

Substances

  • Colloids
  • Ferric Compounds
  • ferric oxide
  • Gold