Gold-catalyzed [3+2] cycloaddition/hydrolytic Michael addition/retro-aldol reactions of propargylic esters tethered to cyclohexadienones

Angew Chem Int Ed Engl. 2011 Nov 18;50(47):11133-7. doi: 10.1002/anie.201104028. Epub 2011 Sep 29.

Authors

Shunyou Cai¹, Zheng Liu, Weibin Zhang, Xinyang Zhao, David Zhigang Wang

Affiliation

¹ Key Laboratory of Chemical Genomics, School of Chemical Biology and Biotechnology, Shenzhen Graduate School of Peking University, Shenzhen University Town, Shenzhen 518055, China.

PMID: 21960469
DOI: 10.1002/anie.201104028

No abstract available

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Aldehydes / chemistry*
Alkynes / chemistry*
Catalysis
Crystallography, X-Ray
Cyclization
Cyclohexenes / chemical synthesis*
Cyclohexenes / chemistry*
Esters
Gold / chemistry*
Molecular Structure
Stereoisomerism

Substances

Aldehydes
Alkynes
Cyclohexenes
Esters
cyclohexadienone
Gold
3-hydroxybutanal