(1,2,3,4-Tetra-hydro-isoquinoline-2-carbo-dithio-ato-κS,S')(thio-cyanato-κN)(tri-phenyl-phosphane)nickel(II)

P Valarmathi; S Thirumaran; S Selvanayagam

doi:10.1107/S1600536811050550

(1,2,3,4-Tetra-hydro-isoquinoline-2-carbo-dithio-ato-κS,S')(thio-cyanato-κN)(tri-phenyl-phosphane)nickel(II)

Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1882. doi: 10.1107/S1600536811050550. Epub 2011 Nov 30.

Authors

P Valarmathi, S Thirumaran, S Selvanayagam

Abstract

The Ni(II) atom in the mononuclear title compound, [Ni(C(10)H(10)NS(2))(NCS)(C(18)H(15)P)], exists within a S(2)PN donor set that defines a distorted square-planar geometry. A significant asymmetry in the Ni-S bond lengths support the less effective trans effect of SCN(-) over PPh(3).