Bis(4-fluoro-benz-yl)bis-(4-phenyl-5-sulfanyl-idene-4,5-dihydro-1,3,4-thio-diazole-2-thiol-ato)tin(IV)

Lei Li; Suyuan Zeng; Nana Yan

doi:10.1107/S1600536811054274

Bis(4-fluoro-benz-yl)bis-(4-phenyl-5-sulfanyl-idene-4,5-dihydro-1,3,4-thio-diazole-2-thiol-ato)tin(IV)

Acta Crystallogr Sect E Struct Rep Online. 2012 Jan;68(Pt 1):m83. doi: 10.1107/S1600536811054274. Epub 2011 Dec 23.

Authors

Lei Li¹, Suyuan Zeng, Nana Yan

Affiliation

¹ College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.

Abstract

In the title complex, [Sn(C(7)H(6)F)(2)(C(8)H(5)N(2)S(3))(2)], including the weak Sn-N inter-actions, the Sn(IV) atom is situated in a distorted trans-octa-hedral geometry, and the equatorial plane is defined by two chelating 4-phenyl-5-sulfanyl-idene-4,5-dihydro-1,3,4-thio-diazole-2-thiol-ate ligands. The apical positions are occupied by two C atoms of 4-fluoro-benzyl groups.