1-Benzoyl-2-thio-biuret

Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):o395. doi: 10.1107/S1600536812000621. Epub 2012 Jan 14.

Abstract

IN THE TITLE COMPOUND [SYSTEMATIC NAME: N-(carbamoyl-carb-a-mo-thio-yl)benzamide], C(9)H(9)N(3)O(2)S, the benzoyl and terminal urea fragments adopt cisoid and transoid conformations, respectively, with respect to the S atom. The benzoyl and thio-biuret groups are almost coplanar, making a dihedral angle of 8.48 (5)°. The mol-ecular structure is stabilized by an intra-molecular N-H⋯O hydrogen bond. In the crystal, N-H⋯O and N-H⋯S hydrogen bonds link the mol-ecules into a sheet parallel to the bc plane.