Total synthesis of (+)-anamarine
- PMID: 22354519
- DOI: 10.1039/c2ob06940g
Total synthesis of (+)-anamarine
Abstract
Total synthesis of (+)-anamarine a polyoxygenated δ-pyranone natural product was accomplished via cross-metathesis protocol starting from 3-butene-1-ol and glycidol. Other key features of this synthetic strategy include use of Sharpless asymmetric epoxidation, dihydroxylation, and deoxygenation-isomerization through allene rearrangement.
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