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. 2012 Apr 7;10(13):2647-55.
doi: 10.1039/c2ob06940g. Epub 2012 Feb 22.

Total synthesis of (+)-anamarine

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Total synthesis of (+)-anamarine

Krishnammagari Suresh Kumar et al. Org Biomol Chem. .

Abstract

Total synthesis of (+)-anamarine a polyoxygenated δ-pyranone natural product was accomplished via cross-metathesis protocol starting from 3-butene-1-ol and glycidol. Other key features of this synthetic strategy include use of Sharpless asymmetric epoxidation, dihydroxylation, and deoxygenation-isomerization through allene rearrangement.

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