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. 2012 May 14;41(18):5458-60.
doi: 10.1039/c2dt30174a. Epub 2012 Mar 12.

Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks

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Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks

Adam F Gross et al. Dalton Trans. .

Abstract

Sodalite zeolitic imidazolate frameworks containing Co (ZIF-67) and Zn (ZIF-8) were synthesized at room temperature under aqueous conditions in 10 min. A trialkylamine deprotonated the 2-methylimidazole ligand and nucleated the frameworks. Furthermore, the ligand acted as a structure directing agent in place of an organic solvent.

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