Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks
- PMID: 22406684
- DOI: 10.1039/c2dt30174a
Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks
Abstract
Sodalite zeolitic imidazolate frameworks containing Co (ZIF-67) and Zn (ZIF-8) were synthesized at room temperature under aqueous conditions in 10 min. A trialkylamine deprotonated the 2-methylimidazole ligand and nucleated the frameworks. Furthermore, the ligand acted as a structure directing agent in place of an organic solvent.
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