Complexes with 3-(pyridin-2-yl)imidazo[1,5-a]pyridine ligands by spontaneous dimerization of pyridine-2-carboxaldehyde within the coordination sphere of manganese(II) in a one-pot reaction

Celedonio M Álvarez; Lucía Álvarez-Miguel; Raúl García-Rodríguez; Daniel Miguel

doi:10.1039/c2dt30453h

Complexes with 3-(pyridin-2-yl)imidazo[1,5-a]pyridine ligands by spontaneous dimerization of pyridine-2-carboxaldehyde within the coordination sphere of manganese(II) in a one-pot reaction

Dalton Trans. 2012 Jun 21;41(23):7041-6. doi: 10.1039/c2dt30453h. Epub 2012 May 3.

Authors

Celedonio M Álvarez¹, Lucía Álvarez-Miguel, Raúl García-Rodríguez, Daniel Miguel

Affiliation

¹ GIR MIOMET IU CINQUIMA/Química Inorgánica, Facultad de Ciencias, Universidad de Valladolid, C/Prado de la Magdalena s/n., E-47071 Valladolid, Spain.

PMID: 22552623
DOI: 10.1039/c2dt30453h

Abstract

Condensation of two molecules of pyridine-2-carboxaldehyde (pyca), in the presence of MnCl(2) and ammonium diethyldithiophosphate, produced, in a one-pot reaction, Mn(II) complexes containing 3-(pyridin-2-yl)imidazo[1,5-a]pyridines as κ(2)(N,N) chelate ligands which could be easily separated from the metal, this being a convenient way to pyridyl-aza-indolizine heterocycles.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Aldehydes / chemistry*
Dimerization*
Imidazoles / chemistry*
Ligands
Manganese / chemistry*
Organometallic Compounds / chemical synthesis
Organometallic Compounds / chemistry*
Pyridines / chemistry*
Quaternary Ammonium Compounds / chemistry

Substances

Aldehydes
Imidazoles
Ligands
Organometallic Compounds
Pyridines
Quaternary Ammonium Compounds
pyridine-2-carboxaldehyde
Manganese