Low-temperature iron-catalyzed depolymerization of polyethers

ChemSusChem. 2012 Jul;5(7):1195-8. doi: 10.1002/cssc.201200125. Epub 2012 May 25.

Abstract

Iron will: The iron-catalyzed depolymerization of a range of polyethers is studied. The products of the depolymerization reactions are chloroesters, which can be used as starting materials for new polymers. In the presence of simple iron salts extraordinary catalyst activities and selectivities are feasible at low temperature.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Catalysis
  • Ethers / chemistry*
  • Iron / chemistry*
  • Polymerization*
  • Temperature*

Substances

  • Ethers
  • Iron