A palladium-catalyzed three-component coupling of arylboronic acids, sulfur dioxide and hydrazines

Chem Commun (Camb). 2012 Aug 11;48(62):7753-5. doi: 10.1039/c2cc33725h. Epub 2012 Jun 29.

Abstract

A novel and efficient route to aryl N-aminosulfonamides via a palladium-catalyzed three-component coupling of arylboronic acids, sulfur dioxide and hydrazines in the presence of a balloon of dioxygen is reported. The reaction proceeded smoothly under mild conditions and DABCO·(SO(2))(2) was used as the source of sulfur dioxide.