Construction of benzosiloles, six- and eight-membered silacyclic skeletons, via a Pd-catalyzed intramolecular Mizoroki-Heck reaction of vinylsilanes

Kunbing Ouyang; Yun Liang; Zhenfeng Xi

doi:10.1021/ol302040j

Construction of benzosiloles, six- and eight-membered silacyclic skeletons, via a Pd-catalyzed intramolecular Mizoroki-Heck reaction of vinylsilanes

Org Lett. 2012 Sep 7;14(17):4572-5. doi: 10.1021/ol302040j. Epub 2012 Aug 10.

Authors

Kunbing Ouyang¹, Yun Liang, Zhenfeng Xi

Affiliation

¹ Beijing National Laboratory for Molecular Sciences (BNLMS), and Institute of Chemistry, Chinese Academy of Sciences (CAS), Beijing 100190, China.

PMID: 22882135
DOI: 10.1021/ol302040j

Abstract

A variety of silacycles including benzosiloles, six- and eight-membered silacyclic skeletons, were efficiently synthesized via a Pd-catalyzed intramolecular Mizoroki-Heck reaction of vinylsilanes.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Catalysis
Cyclization
Molecular Structure
Organosilicon Compounds / chemical synthesis*
Organosilicon Compounds / chemistry*
Palladium / chemistry*
Vinyl Compounds / chemistry*

Substances

Organosilicon Compounds
Vinyl Compounds
Palladium