The sweetness concentration-response of r,r-monatin, a naturally occurring high-potency sweetener

J Food Sci. 2012 Oct;77(10):S362-4. doi: 10.1111/j.1750-3841.2012.02885.x. Epub 2012 Aug 27.

Abstract

Monatin, known by the common and usual name arruva, is a zero-calorie, high-potency sweetener naturally occurring in the plant Sclerochiton ilicifolius A.Meeuse. The sweetness concentration-response (C-R) behavior of the most potent isomer (R,R-) in room-temperature (21 °C) water was determined using two-alternative forced choice discrimination tests with a minimum of 69 tasters. Results were processed by a method previously published to obtain isosweet concentrations of sucrose for 8 monatin concentrations up to 240 mg/L. These were used to construct a C-R plot. The equation for the resultant hyperbolic curve relating sucrose equivalent (SE,%) to monatin concentration ([monatin], mg/L) was SE = 26.7 ×[monatin]/(69.6 +[monatin]). R,R-monatin has a potency above 3000 at 5% sucrose equivalent, making it one of the most potently sweet naturally occurring substances known.

Practical application: Monatin is a naturally occurring, zero-calorie, high-potency sweetener. We have measured the sweetness of monatin over a range of concentrations. This information will help developers of zero-, low- and reduced-calorie products formulate with monatin.

MeSH terms

  • Glutamic Acid / analogs & derivatives*
  • Glutamic Acid / chemistry
  • Humans
  • Indoles / chemistry*
  • Sucrose / chemistry
  • Sweetening Agents / chemistry*
  • Taste*

Substances

  • 4-hydroxy-4-(indol-3-ylmethyl)glutamic acid
  • Indoles
  • Sweetening Agents
  • Glutamic Acid
  • Sucrose