Gold(I) and platinum(II) switch: a post-Ugi intramolecular hydroarylation to pyrrolopyridinones and pyrroloazepinones

Chem Commun (Camb). 2012 Nov 14;48(88):10916-8. doi: 10.1039/c2cc35900f. Epub 2012 Oct 3.

Abstract

A regioselective approach for the synthesis of pyrrolopyridinones and pyrroloazepinones is reported employing an Ugi reaction followed by a gold(I) or platinum(II) catalyzed intramolecular hydroarylation.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Azepines / chemistry*
  • Catalysis
  • Cyclization
  • Gold / chemistry*
  • Platinum / chemistry*
  • Pyridones / chemistry*

Substances

  • Azepines
  • Pyridones
  • Platinum
  • Gold