We demonstrate the use of a large-pitch Kagome-lattice hollow-core photonic crystal fiber probe for Raman spectroscopy. The large transmission bandwidth of the fiber enables both the excitation and Raman beams to be transmitted through the same fiber. As the excitation beam is mainly transmitted through air inside the hollow core, the silica luminescence background is reduced by over 2 orders of magnitude as compared to standard silica fiber probes, removing the need for fiber background subtraction.