CO2 superabsorption in a paddlewheel-type Ru dimer chain compound: gate-open performance dependent on inter-chain interactions

Wataru Kosaka; Kayo Yamagishi; Hiroki Yoshida; Ryotaro Matsuda; Susumu Kitagawa; Masaki Takata; Hitoshi Miyasaka

doi:10.1039/c2cc36153a

CO2 superabsorption in a paddlewheel-type Ru dimer chain compound: gate-open performance dependent on inter-chain interactions

Chem Commun (Camb). 2013 Feb 25;49(16):1594-6. doi: 10.1039/c2cc36153a.

Authors

Wataru Kosaka¹, Kayo Yamagishi, Hiroki Yoshida, Ryotaro Matsuda, Susumu Kitagawa, Masaki Takata, Hitoshi Miyasaka

Affiliation

¹ Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan.

PMID: 23174816
DOI: 10.1039/c2cc36153a

Abstract

A porous one-dimensional coordination chain compound, [Ru(2)(p-F-PhCO(2))(4)(phz)] (; p-F-PhCO(2)(-) = para-fluorobenzoate; phz = phenazine) derived by drying its nitrobenzene-solvated compound, specifically adsorbs CO(2) at 195 K in a stepwise sorption manner.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Adsorption
Carbon Dioxide / chemistry*
Coordination Complexes / chemistry*
Dimerization
Models, Molecular
Nitrobenzenes / chemistry
Porosity
Ruthenium / chemistry*
Surface Properties

Substances

Coordination Complexes
Nitrobenzenes
Carbon Dioxide
Ruthenium
nitrobenzene