Based on the biomineralization assembly concept, a simple and inexpensive biomimetic sol-gel method is found to synthesize high-performance mesoporous LiFePO(4) (HPM-LFP). The key step of this approach is to apply Baker's yeast cells as both a structural template and a biocarbon source. The formation mechanism of ordered hierarchical mesoporous network structure is revealed by characterizing its morphology and microstructure. The HPM-LFP exhibits outstanding electrochemical performances. The HPM-LFP has a high discharge capacity (about 153 mAh g(-1) at a 0.1 C rate), only 2% capacity loss from the initial value after 100 cycles at a current density of 0.1 C. This simple and potentially universal design strategy is currently being pursued in the synthesis of an ideal cathode-active material for high power applications.
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