Powering up the future: radical polymers for battery applications

Adv Mater. 2012 Dec 18;24(48):6397-409. doi: 10.1002/adma.201203119.

Abstract

Our society's dependency on portable electric energy, i.e., rechargeable batteries, which permit power consumption at any place and in any time, will eventually culminate in resource wars on limited commodities like lithium, cobalt, and rare earth metals. The substitution of conventional metals as means of electric charge storage by organic and polymeric materials, which may ultimately be derived from renewable resources, appears to be the only feasible way out. In this context, the novel class of organic radical batteries (ORBs) excelling in rate capability (i.e., charging speed) and cycling stability (>1000 cycles) sets new standards in battery research. This review examines stable nitroxide radical bearing polymers, their processing to battery systems, and their promising performance.

Publication types

  • Research Support, Non-U.S. Gov't
  • Review

MeSH terms

  • Electric Power Supplies*
  • Electrochemical Techniques
  • Electrodes
  • Free Radicals / chemical synthesis
  • Free Radicals / chemistry
  • Nitrogen Oxides / chemical synthesis
  • Nitrogen Oxides / chemistry
  • Polymers / chemical synthesis*
  • Polymers / chemistry

Substances

  • Free Radicals
  • Nitrogen Oxides
  • Polymers