Signatures of charge inhomogeneities in the infrared spectra of topological insulators Bi2Se3, Bi2Te3 and Sb2Te3

J Phys Condens Matter. 2013 Feb 20;25(7):075501. doi: 10.1088/0953-8984/25/7/075501. Epub 2013 Jan 17.

Abstract

We present the results of an infrared spectroscopy study of topological insulators Bi(2)Se(3), Bi(2)Te(3) and Sb(2)Te(3). Reflectance spectra of all three materials look similar, with a well defined plasma edge. However, there are some important differences. Most notably, as temperature decreases the plasma edge shifts to lower frequencies in Bi(2)Se(3), whereas in Bi(2)Te(3) and Sb(2)Te(3) it shifts to higher frequencies. In the loss function spectra we identify asymmetric broadening of the plasmon, and assign it to the presence of charge inhomogeneities. It remains to be seen if charge inhomogeneities are characteristic of all topological insulators, and whether they are of intrinsic or extrinsic nature.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Antimony / chemistry*
  • Bismuth / chemistry*
  • Electric Conductivity
  • Selenium / chemistry*
  • Spectrophotometry, Infrared*
  • Static Electricity
  • Tellurium / chemistry*

Substances

  • bismuth telluride
  • Antimony
  • Selenium
  • Tellurium
  • Bismuth