Identification and quantification of anthocyanins in Kyoho grape juice-making pomace, Cabernet Sauvignon grape winemaking pomace and their fresh skin

J Sci Food Agric. 2013 Apr;93(6):1404-11. doi: 10.1002/jsfa.5907. Epub 2013 Feb 11.

Abstract

Background: The anthocyanins of Kyoho grape juice-making pomace, Cabernet Sauvignon grape winemaking pomace and their fresh skin were identified and quantified by high-performance liquid chromatography-tandem mass spectrometry, and the influence of processing on the anthocyanin profiles was investigated.

Results: Twenty-three and 16 anthocyanins were found in fresh skin of Kyoho and Cabernet Sauvignon grapes, respectively. Malvidin 3-(trans)-coumaroyl-5-diglucoside and malvidin 3-glucoside were the most abundant anthocyanin in fresh skin of Kyoho and Cabernet Sauvignon grapes, respectively. The cis and trans isomers of malvidin 3-coumaroyl-5-diglucoside are reported in Kyoho grape for the first time. In addition, the anthocyanin content of juice-making pomace of Kyoho grapes and winemaking pomace of Cabernet Sauvignon grapes was significantly lower than the fresh skin samples (p < 0.05). The percentage variation of non-acylated anthocyanins was lower than that of acylated anthocyanins in all pomace samples.

Conclusion: Kyoho grape and Cabernet Sauvignon grape showed distinctive anthocyanin profiles. Juice-making pomace is a better source of anthocyanins for use in functional foods than winemaking pomace.

Keywords: Cabernet Sauvignon; Kyoho; anthocyanin composition; grape pomace.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acylation
  • Anthocyanins / analysis*
  • Beverages / analysis*
  • Diet
  • Food Handling / methods*
  • Fruit / chemistry*
  • Glucosides / analysis
  • Humans
  • Species Specificity
  • Vitis / chemistry*
  • Vitis / classification
  • Wine / analysis

Substances

  • Anthocyanins
  • Glucosides
  • malvidin-3-glucoside