Chemically crosslinked isoreticular metal-organic frameworks

Chem Commun (Camb). 2013 Apr 21;49(31):3200-2. doi: 10.1039/c3cc40635k. Epub 2013 Mar 14.

Abstract

Herein we report the synthesis of canonical isoreticular metal-organic frameworks (IRMOFs) containing interligand crosslinks. Chemically crosslinking two molecules of 2-amino-1,4-benzene dicarboxylic acid (NH2-BDC) gives ligands that readily form IRMOF-1 analogs, producing crosslinked MOFs that may be designed to have novel properties.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Dicarboxylic Acids / chemical synthesis
  • Dicarboxylic Acids / chemistry
  • Metals / chemistry*
  • Organic Chemicals / chemistry*
  • Organometallic Compounds / chemical synthesis
  • Organometallic Compounds / chemistry
  • Temperature

Substances

  • Dicarboxylic Acids
  • Metals
  • Organic Chemicals
  • Organometallic Compounds
  • zinc benzenedicarboxylate