Abstract
By the reaction of amines with alkylborane reagents in the presence of a catalytic amount of copper(II) acetate Cu(OAc)2 and di-tert-butyl peroxide, a cross-coupling reaction proceeded and alkylated amines were obtained in good to excellent yields. Phenols are also applicable for this reaction, and the corresponding alkyl aryl ethers were produced.
Publication types
-
Research Support, Non-U.S. Gov't
MeSH terms
-
Alkylation
-
Amines / chemistry*
-
Boranes / chemistry*
-
Catalysis
-
Combinatorial Chemistry Techniques
-
Copper / chemistry*
-
Ethers / chemical synthesis*
-
Ethers / chemistry
-
Indicators and Reagents
-
Molecular Structure
-
Peroxides
-
Phenols / chemistry*
Substances
-
Amines
-
Boranes
-
Ethers
-
Indicators and Reagents
-
Peroxides
-
Phenols
-
di-tert-butyl peroxide
-
Copper