Self-assembly of a molecular crown as a structural analogue of calix[4]arene to modify Keggin anions

Aixiang Tian; Xiaoling Lin; Jun Ying; Juwen Zhang; Hongyan Lin; Guocheng Liu; Dan Zhao; Na Li; Xiuli Wang

doi:10.1039/c3dt50800e

Self-assembly of a molecular crown as a structural analogue of calix[4]arene to modify Keggin anions

Dalton Trans. 2013 Jul 21;42(27):9809-12. doi: 10.1039/c3dt50800e. Epub 2013 May 23.

Authors

Aixiang Tian¹, Xiaoling Lin, Jun Ying, Juwen Zhang, Hongyan Lin, Guocheng Liu, Dan Zhao, Na Li, Xiuli Wang

Affiliation

¹ Department of Chemistry, Bohai University, Jinzhou, 121000, PR China.

PMID: 23698455
DOI: 10.1039/c3dt50800e

Abstract

Four Ag(I) ions are linked by four 5-phenyl-1H-tetrazole (Hptz) units to form a molecular crown [Ag4(ptz)4] as a structural analogue of calix[4]arene, which are further supported by Keggin anions to build a 2D layer containing two kinds of cycles, [Ag8(ptz)4(HPW(V)2W(VI)10O40)]·2H2O (1).

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Anions / chemistry
Calixarenes / chemistry*
Models, Molecular
Molecular Structure
Organometallic Compounds / chemical synthesis*
Organometallic Compounds / chemistry
Phenols / chemistry*
Silver / chemistry

Substances

Anions
Organometallic Compounds
Phenols
calix(4)arene
Calixarenes
Silver