Designing ternary cocrystals with hydrogen bonds and halogen bonds

Chem Commun (Camb). 2013 Sep 14;49(71):7791-3. doi: 10.1039/c3cc43822h.

Abstract

A graded selection of hydrogen bonds and halogen bonds allows for the isolation of 2 : 1 : 1 ternary cocrystals of the general form 4-nitrobenzamide : diacid : 1,4-dihalogenated benzene, which are mediated by the amide-acid and I···O2N supramolecular synthons.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amides / chemistry
  • Benzene / chemistry
  • Crystallization
  • Halogens / chemistry*
  • Hydrogen Bonding
  • Oxalic Acid / chemistry

Substances

  • Amides
  • Halogens
  • Oxalic Acid
  • Benzene