Effect of particle size on ferroelectric and magnetic properties of BiFeO₃ nanopowders

Nanotechnology. 2013 Sep 6;24(35):355701. doi: 10.1088/0957-4484/24/35/355701. Epub 2013 Aug 6.

Abstract

The ferroelectric and magnetic behaviour of multiferroic BiFeO₃ nanoparticles has been studied using piezoresponse force microscopy (PFM), Mössbauer spectroscopy and SQUID magnetometry. The results of the PFM studies indicate a decay of the spontaneous polarization with decreasing particle size. Nevertheless, particles with diameter ∼50 nm still manifest ferroelectric behaviour. At the same time these particles are weakly ferromagnetic. The Mössbauer spectroscopy studies prove that the weak ferromagnetic state is due to non-compensated surface spins rather than distortions of the cycloidal spin structure characteristic for bulk BiFeO₃.

Publication types

  • Research Support, Non-U.S. Gov't