Abstract
Vinyl silyl ethers and disiloxanes can now be prepared from aryl-substituted alkenes and related substrates using a silyl-Heck reaction. The reaction employs a commercially available catalyst system and mild conditions. This work represents a highly practical means of accessing diverse classes of vinyl silyl ether substrates in an efficient and direct manner with complete regiomeric and geometric selectivity.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Alkenes / chemistry
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Ethers / chemical synthesis*
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Ethers / chemistry
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Molecular Structure
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Silanes / chemical synthesis*
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Silanes / chemistry
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Vinyl Compounds / chemical synthesis*
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Vinyl Compounds / chemistry
Substances
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Alkenes
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Ethers
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Silanes
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Vinyl Compounds
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disiloxane