Distributed Raman amplification (DRA) based on ultra-long fiber laser (UL-FL) pumping with a ring cavity is promising for repeaterless transmission and sensing. In this work, the characteristics (including gain, nonlinear impairment and noise figure) for forward and backward pumping of the ring-cavity based DRA scheme are fully investigated. Furthermore, as a typical application of the proposed configuration, ultra-long-distance distributed sensing with Brillouin optical time-domain analysis (BOTDA) over 142.2 km fiber with 5m spatial resolution and ± 1.5 °C temperature uncertainty is achieved, without any repeater. The key point for the significant performance improvement is the system could offer both of uniform gain distribution and considerably suppressed pump-probe relative intensity noise (RIN) transfer, by optimized design of system structure and parameters.