Stereoselective synthesis of vinyl triflones and heteroaryl triflones through anionic O→C(vinyl) and N→C(vinyl) trifluoromethanesulfonyl migration reactions

Angew Chem Int Ed Engl. 2013 Nov 25;52(48):12628-31. doi: 10.1002/anie.201307535. Epub 2013 Oct 15.

Authors

Xiu-Hua Xu¹, Misaki Taniguchi, Xin Wang, Etsuko Tokunaga, Tomohiro Ozawa, Hideki Masuda, Norio Shibata

Affiliation

¹ Department of Frontier Materials&Department of Nanopharmaceutical Science, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555 (Japan).

PMID: 24249553
DOI: 10.1002/anie.201307535

No abstract available

Keywords: alkenes; lithiation; rearrangement; stereoselectivity; synthetic methods.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Chlorofluorocarbons, Methane / chemistry*
Halogenation
Stereoisomerism
Vinyl Compounds / chemical synthesis*
Vinyl Compounds / chemistry

Substances

Chlorofluorocarbons, Methane
Vinyl Compounds
fluoroform