This report investigates the impact of droplet temperature on the head-on collision of binary droplets on a superhydrophobic surface. Understanding droplet collision is critical to many fundamental processes and industrial applications. There are many factors, including collision speed, collision angle, and droplet composition, that influence the outcome of the collision between binary droplets. This work provides the first experimental study of the influence of droplet temperature on the collision of binary droplets. As the droplet temperature increases, the possibility increases for the two droplets to coalesce after collision. The findings in this study can be extended to collision of droplets under other conditions where control of the droplet temperature is feasible. Such findings will also be beneficial to applications that involve droplet collision, such as in ink-jet printing, steam turbines, engine ignition, and spraying cooling.