Near-infrared reflectance spectroscopy as a rapid and non-destructive analysis tool for curcuminoids in turmeric

Phytochem Anal. 2014 Sep-Oct;25(5):445-52. doi: 10.1002/pca.2514. Epub 2014 Apr 1.

Abstract

Introduction: Turmeric has been widely used in curry powders as the main spice. Conventional chemical analysis such as high-performance liquid chromatography (HPLC) may take several hours to extract curcuminoids and prepare samples in many turmeric processing industries.

Objective: This study was conducted to evaluate curcuminoids in turmeric powder using near-infrared reflectance spectroscopy (NIRS).

Methods: All spectral acquisition ranged from 1100 to 2500 nm and a chemometrics analysis using partial least-squares (PLS) regression was performed to quantify the contents of individual curcuminoids. The HPLC was carried out (n = 129) to develop a PLS model based on the reference values.

Results: High correlation coefficient (R(2) > 0.93) and low standard error of cross-validation (SECV < 0.20 g/100 g) and standard error of prediction (SEP < 0.13 g/100 g) values were obtained for precision and accuracy. In addition, the ratio of prediction to deviation (RPD > 2.65) values was also calculated.

Conclusion: Our results indicate that NIRS could be utilised as a control procedure or as an alternative rapid and effective quantification method.

Keywords: NIR spectroscopy; curcuminoids; non-destructive analysis; quantification; turmeric.

MeSH terms

  • Curcuma / chemistry*
  • Curcumin / analogs & derivatives*
  • Curcumin / chemistry*
  • Spectrophotometry, Infrared / methods*

Substances

  • Curcumin