Abstract
Ir catalysts supported by bidentate silyl ligands that contain P- or N-donors are shown to effect ortho borylations for a range of substituted aromatics. The substrate scope is broad, and the modular ligand synthesis allows for flexible catalyst design.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Boron Compounds / chemical synthesis*
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Boron Compounds / chemistry
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Catalysis
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Chelating Agents / chemical synthesis*
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Chelating Agents / chemistry
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Coordination Complexes / chemistry*
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Iridium / chemistry
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Molecular Structure
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Nitrogen / chemistry*
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Organophosphorus Compounds / chemical synthesis*
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Organophosphorus Compounds / chemistry
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Organosilicon Compounds / chemical synthesis*
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Organosilicon Compounds / chemistry
Substances
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Boron Compounds
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Chelating Agents
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Coordination Complexes
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Organophosphorus Compounds
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Organosilicon Compounds
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Iridium
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Nitrogen