Efficient alkene hydrogenation over a magnetically recoverable and recyclable Fe3O4@GO nanocatalyst using hydrazine hydrate as the hydrogen source

Chem Commun (Camb). 2014 Oct 18;50(81):12095-7. doi: 10.1039/c4cc04770b.

Abstract

Magnetic Fe3O4 nanoparticles embedded in graphene oxide (Fe3O4@GO) behave as a highly efficient and reusable heterogeneous nanocatalyst for alkene hydrogenation in EtOH at 80 °C temperature using hydrazine hydrate as the hydrogen source to deliver the corresponding alkanes in good to excellent yields together with high TOF (>4500 h(-1)) within a 4-20 h reaction time.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alkenes / chemistry*
  • Catalysis
  • Ethanol / chemistry
  • Ferrosoferric Oxide / chemistry
  • Graphite / chemistry*
  • Hydrazines / chemistry*
  • Hydrogen / chemistry
  • Hydrogenation
  • Magnetics
  • Nanoparticles / chemistry*
  • Oxides / chemistry
  • Temperature

Substances

  • Alkenes
  • Hydrazines
  • Oxides
  • hydrazine
  • Ethanol
  • Graphite
  • Hydrogen
  • Ferrosoferric Oxide