Abstract
Silver-catalyzed cascade difunctionalization of N-(p-methoxyaryl)propiolamides coupled with dearomatization was achieved and used to regiospecifically construct a variety of phosphorylated aza-decenones bearing adjacent quaternary stereocenters under mild conditions in moderate to excellent yields.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Amides / chemistry*
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Aza Compounds / chemical synthesis*
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Aza Compounds / chemistry
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Carbon / chemistry*
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Catalysis
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Ketones / chemical synthesis*
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Ketones / chemistry
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Molecular Structure
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Phosphorus / chemistry*
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Silver / chemistry*
Substances
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Amides
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Aza Compounds
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Ketones
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Phosphorus
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Silver
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Carbon