Abstract
A metal-dependent and complementary catalytic method to synthesize the cyclohexadienes has been developed. When gold or indium salts were used as catalysts, 1,3-cyclohexadiene (1,3-CHD) could be obtained; when Cu(OTf)2 was used as the catalyst, however, another isomer 2,4-cyclohexadiene (2,4-CHD) was furnished instead.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Alkenes / chemistry
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Alkynes / chemistry
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Catalysis
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Chemistry Techniques, Synthetic
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Cyclohexenes / chemical synthesis*
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Cyclohexenes / chemistry*
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Isomerism
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Metals / chemistry*
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Substrate Specificity
Substances
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Alkenes
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Alkynes
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Cyclohexenes
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Metals
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1,3-cyclohexadiene