Crystal structure of 3-({[(morpholin-4-yl)carbono-thio-yl]sulfan-yl}acet-yl)phenyl benzoate

Acta Crystallogr Sect E Struct Rep Online. 2014 Oct 24;70(Pt 11):400-2. doi: 10.1107/S1600536814023265. eCollection 2014 Nov 1.

Abstract

In the title compound, C20H19NO4S2, the morpholine ring adopts the expected chair conformation. The central phenyl ring makes dihedral angles of 67.97 (4) and 7.74 (3)°, respectively, with the benzoate phenyl ring and the morpholine mean plane. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds, forming zigzag chains along the b-axis direction. C-H⋯π inter-actions link centrosymmetrically related mol-ecules, reinforcing the three-dimensional structure.

Keywords: crystal structure; hydrogen bonding; phenyl benzoates.