Silica wet gels were prepared from hydrolysis of tetraethoxysilane (TEOS) with additions of sodium dodecyl sulfate (SDS). The surfactant was removed after gelation. Wet gels exhibited mass-fractal structure with mass-fractal dimension D (typically around 2.25) in a length scale extending from a characteristic size ξ (typically about 10 nm) of the mass-fractal domains to a characteristic size a0 (typically between 0.3 and 0.4 nm) of the primary particles building up the fractal domains. ξ increased while D and a0 diminished slightly as the SDS quantity increased. Aerogels with typical specific surface of 1000 m(2)/g and density of 0.20 g/cm(3) were obtained by supercritical drying of the wet gels after washing with ethanol and n-hexane. The pore volume and the mean pore size increased with the increase of the SDS quantity. The aerogels presented most of the mass-fractal characteristics of the original wet gels at large length scales and exhibited at a higher resolution level at about 0.7 nm a crossover to a mass-surface fractal structure, with apparent mass-fractal dimension Dm ∼ 2.4 and surface-fractal dimension Ds ∼ 2.6, as inferred from small-angle X-ray scattering (SAXS) and nitrogen adsorption data.