Abstract
Addition of functionalized aryl, heteroaryl or adamantyl zinc reagents to various nitroso-arenes in the presence of magnesium salts and LiCl in THF produces after a reductive work-up with FeCl2 and NaBH4 in ethanol the corresponding polyfunctional secondary amines in high yields.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Amines / chemistry*
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Borohydrides / chemistry
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Ferrous Compounds / chemistry
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Lithium Chloride / chemistry
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Magnesium / chemistry
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Nitroso Compounds / chemistry*
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Zinc / chemistry*
Substances
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Amines
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Borohydrides
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Ferrous Compounds
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Nitroso Compounds
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sodium borohydride
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Lithium Chloride
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Magnesium
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Zinc
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ferrous chloride