Iodide-capped PbS quantum dots: full optical characterization of a versatile absorber

Adv Mater. 2015 Mar 4;27(9):1533-9. doi: 10.1002/adma.201404921. Epub 2015 Jan 21.

Abstract

Lead sulfide quantum dots represent an emerging photovoltaic absorber material. While their associated optical qualities are true for the colloidal solution phase, they change upon processing into thin-films. A detailed view to the optical key-parameters during solid-film development is presented and the limits and outlooks for this versatile and promising absorber are discussed.

Keywords: atomic ligands; lead sulfide quantum dots; quantum dot photovoltaic cells; spectroscopic ellipsometry; time-resolved photoluminescence.