Unique kinked semiconductor-metal Au-Ag2S-ZnS and Au-Ag2S-ZnS-Au heteronanorods have been synthesized for the first time by a seed-mediated growth method. A plausible mechanism for the formation of kinked heteronanorods is proposed. The catalytic activity of such novel kinked semiconductor-metal heteronanorods with selective deposition and uniform morphology is also investigated via a model reaction based on the reduction of 4-nitrophenol by NaBH4.