Enhancing mechanical performance of a covalent self-healing material by sacrificial noncovalent bonds

J Am Chem Soc. 2015 Apr 15;137(14):4846-50. doi: 10.1021/jacs.5b01601. Epub 2015 Apr 1.

Abstract

Polymers that repair themselves after mechanical damage can significantly improve their durability and safety. A major goal in the field of self-healing materials is to combine robust mechanical and efficient healing properties. Here, we show that incorporation of sacrificial bonds into a self-repairable network dramatically improves the overall mechanical properties. Specifically, we use simple secondary amide side chains to create dynamic energy dissipative hydrogen bonds in a covalently cross-linked polymer network, which can self-heal via olefin cross-metathesis. We envision that this straightforward sacrificial bonding strategy can be employed to improve mechanical properties in a variety of self-healing systems.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Amides / chemistry
  • Hydrogen Bonding
  • Mechanical Phenomena*
  • Polymers / chemistry*
  • Rheology
  • Tensile Strength

Substances

  • Amides
  • Polymers