A simple and efficient method for the preparation of 5-hydroxy-3-acyltetramic acids

Beilstein J Org Chem. 2015 Mar 6:11:323-7. doi: 10.3762/bjoc.11.37. eCollection 2015.

Abstract

Oxidation of the bisenolates of 3-acyltetramic acid to the corresponding 5-hydroxylated compounds using molecular oxygen is reported. The deprotection of the resulting compounds was also achieved.

Keywords: heterocyclic chemistry; hydroxylation; natural products; tetramic acids.