Dissolution chemistry and biocompatibility of silicon- and germanium-based semiconductors for transient electronics

ACS Appl Mater Interfaces. 2015 May 6;7(17):9297-305. doi: 10.1021/acsami.5b02526. Epub 2015 Apr 23.

Abstract

Semiconducting materials are central to the development of high-performance electronics that are capable of dissolving completely when immersed in aqueous solutions, groundwater, or biofluids, for applications in temporary biomedical implants, environmentally degradable sensors, and other systems. The results reported here include comprehensive studies of the dissolution by hydrolysis of polycrystalline silicon, amorphous silicon, silicon-germanium, and germanium in aqueous solutions of various pH values and temperatures. In vitro cellular toxicity evaluations demonstrate the biocompatibility of the materials and end products of dissolution, thereby supporting their potential for use in biodegradable electronics. A fully dissolvable thin-film solar cell illustrates the ability to integrate these semiconductors into functional systems.

Keywords: biocompatible materials; bioresorbable electronics; dissoluble semiconductors; thin-film solar cells; transient electronics.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Biocompatible Materials / chemistry
  • Biocompatible Materials / toxicity
  • Cell Survival / drug effects*
  • Crystallization / methods
  • Electric Power Supplies
  • Electronics / instrumentation
  • Equipment Design
  • Equipment Failure Analysis
  • Germanium / chemistry*
  • Germanium / radiation effects
  • Germanium / toxicity*
  • Light
  • Materials Testing
  • Semiconductors*
  • Silicon / chemistry*
  • Silicon / toxicity*
  • Solar Energy

Substances

  • Biocompatible Materials
  • Germanium
  • Silicon