6,7-Di-chloro-2,3-bis(pyridin-2-yl)quinox-aline

Acta Crystallogr E Crystallogr Commun. 2015 Jan 10;71(Pt 2):o107. doi: 10.1107/S2056989015000055. eCollection 2015 Feb 1.

Abstract

The title compound, C18H10Cl2N4, synthesized by the condensation reaction between 4,5-di-chloro-benzene-1,2-di-amine and 1,2-di(pyridin-2-yl)ethane-1,2-dione in boiling acetic acid, has a nearly planar quinoxaline moiety [maximum deviation = 0.070 (1) Å] whose mean plane makes dihedral angles of 40.51 (2) and 39.29 (3)° with the pyridine rings. Within the unit cell, there are no classical hydrogen bonds. Molecules in the structure pack with π-π stacking contacts between the quinoxaline units and nearby pyridine rings with an intercentroid distance of 3.7676 (9) Å.

Keywords: crystal structure; quinoxaline.