Effect of carboxylesterase 1 c.428G > A single nucleotide variation on the pharmacokinetics of quinapril and enalapril

Br J Clin Pharmacol. 2015 Nov;80(5):1131-8. doi: 10.1111/bcp.12667. Epub 2015 Jun 11.

Abstract

Aim: The aim of the present study was to investigate the effects of the carboxylesterase 1 (CES1) c.428G > A (p.G143E, rs71647871) single nucleotide variation (SNV) on the pharmacokinetics of quinapril and enalapril in a prospective genotype panel study in healthy volunteers.

Methods: In a fixed-order crossover study, 10 healthy volunteers with the CES1 c.428G/A genotype and 12 with the c.428G/G genotype ingested a single 10 mg dose of quinapril and enalapril with a washout period of at least 1 week. Plasma concentrations of quinapril and quinaprilat were measured for up to 24 h and those of enalapril and enalaprilat for up to 48 h. Their excretion into the urine was measured from 0 h to 12 h.

Results: The area under the plasma concentration-time curve from 0 h to infinity (AUC0-∞) of active enalaprilat was 20% lower in subjects with the CES1 c.428G/A genotype than in those with the c.428G/G genotype (95% confidence interval of geometric mean ratio 0.64, 1.00; P = 0.049). The amount of enalaprilat excreted into the urine was 35% smaller in subjects with the CES1 c.428G/A genotype than in those with the c.428G/G genotype (P = 0.044). The CES1 genotype had no significant effect on the enalaprilat to enalapril AUC0-∞ ratio or on any other pharmacokinetic or pharmacodynamic parameters of enalapril or enalaprilat. The CES1 genotype had no significant effect on the pharmacokinetic or pharmacodynamic parameters of quinapril.

Conclusions: The CES1 c.428G > A SNV decreased enalaprilat concentrations, probably by reducing the hydrolysis of enalapril, but had no observable effect on the pharmacokinetics of quinapril.

Keywords: CES1; carboxylesterase; enalapril; p.G143E; quinapril; rs71647871.

Publication types

  • Clinical Trial
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adult
  • Angiotensin-Converting Enzyme Inhibitors / blood
  • Angiotensin-Converting Enzyme Inhibitors / pharmacokinetics
  • Angiotensin-Converting Enzyme Inhibitors / pharmacology
  • Angiotensin-Converting Enzyme Inhibitors / urine
  • Blood Pressure / drug effects
  • Carboxylic Ester Hydrolases / genetics*
  • Cross-Over Studies
  • Enalapril / blood
  • Enalapril / pharmacokinetics*
  • Enalapril / pharmacology
  • Enalapril / urine
  • Enalaprilat / blood
  • Enalaprilat / urine
  • Female
  • Genotype
  • Healthy Volunteers
  • Heart Rate / drug effects
  • Humans
  • Male
  • Polymorphism, Single Nucleotide / genetics*
  • Quinapril
  • Tetrahydroisoquinolines / blood
  • Tetrahydroisoquinolines / pharmacokinetics*
  • Tetrahydroisoquinolines / pharmacology
  • Tetrahydroisoquinolines / urine
  • Young Adult

Substances

  • Angiotensin-Converting Enzyme Inhibitors
  • Tetrahydroisoquinolines
  • quinaprilat
  • Enalapril
  • Carboxylic Ester Hydrolases
  • CES1 protein, human
  • Enalaprilat
  • Quinapril