Synthesis of magnetron sputtered WO₃ nanoparticles-degradation of 2-chloroethyl ethyl sulfide and dimethyl methyl phosphonate

Monu Verma; Ramesh Chandra; Vinod Kumar Gupta

doi:10.1016/j.jcis.2015.04.039

Synthesis of magnetron sputtered WO₃ nanoparticles-degradation of 2-chloroethyl ethyl sulfide and dimethyl methyl phosphonate

J Colloid Interface Sci. 2015 Sep 1:453:60-68. doi: 10.1016/j.jcis.2015.04.039. Epub 2015 Apr 22.

Authors

Monu Verma¹, Ramesh Chandra², Vinod Kumar Gupta³

Affiliations

¹ Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247667, India; Institute Instrumentation Centre, Indian Institute of Technology Roorkee, Roorkee 247667, India.
² Institute Instrumentation Centre, Indian Institute of Technology Roorkee, Roorkee 247667, India.
³ Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247667, India; Center for Environment and Water, Research Institute, King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia; Department of Applied Sciences, University of Johannesburg, Johannesburg, South Africa. Electronic address: vinodfcy@gmail.com.

PMID: 25965433
DOI: 10.1016/j.jcis.2015.04.039

Abstract

In the present study, tungsten oxide nanoparticles were synthesized using DC magnetron sputtering and investigated their potential for decontamination of 2-chloroethyl ethyl sulfide (CEES) and dimethyl methyl phosphonate (DMMP). The tungsten oxide nanoparticles were characterized by Powder XRD, FE-SEM, EDS, TEM, TGA, N2-BET and FT-IR techniques. The XRD patterns of as-deposited and post annealed tungsten oxide nanoparticles reveal that the crystallite size of detected monoclinic phase WO3 nanoparticle was increased with increasing annealing temperatures. The phase and increase in particles size of WO3 nanoparticles were also confirmed by Raman and TEM analyses. The obtained surface area (∼63-33 m(2)/g) of magnetron sputtered WO3 nanoparticles was found to be enhanced significantly as compared to reported surface area of WO3 nanoparticles synthesis by various techniques. The study of degradation reactions of CEES and DMMP on the surface of obtained nanoparticles was carried out by using GC and GC-MS techniques. The decontamination reactions were found to be pseudo first order steady state with rate constant (k) and half life values 0.143-0.109 h(-1) and 4.82-6.49 h for CEES and 0.018-0.010 h(-1) and 36.87-66.65 h for DMMP, respectively. The FT-IR data reveal the role of hydrolysis reactions in the decontamination of CEES as well as DMMP.

Keywords: Adsorption; Decontamination; Nanoparticles; Sputtering; TEM.